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07-25
2023
A facile synthetic approach based on thieno[3,4-c]pyrrole-4,6...
Lin-Yong Xu, Yuan Gao,Wei Wang, Yiming Shao, Mingxia Chen, Xinrong Yang, Yuang Fu, Meimei Zhang, Xinhui Lu, Rui Sun and Jie Min.Energy & Environmental Science(闵杰)Abstract: To realize the application of organic solar cells (OSCs), emphasis must be placed on reducing material cost, which is one of the golden triangle elements. One key strategy to address this issue is to optimize the ...
07-25
2023
Axial chirality reversal and enantioselective access to Si-st...
Chenyu Jin,Xiaoqian He,Shaowei Chen,Zhuanzhuan Guo,Yu Lan,Xiao Shen.Chem(沈晓、蓝宇)Abstract: Selective hydrosilylation of 1,3-enynes is challenging because of the competing 1,2-, 1,4-, 4,3-hydrosilylation and sequential double hydrosilylation. Herein, we report a Cu-catalyzed enantioselective 1,4-hydrosilylation of 1,3-enynes. The reaction is amenable not only to preparing chiral ...
07-22
2023
Cobalt-catalysed allylic fluoroalkylation of terpenes
Shengchun Wang,Demin Ren,Zhao Liu,Dali Yang,Pengjie Wang,Yiming Gao,Xiaotian Qi &Aiwen Lei.Nature Synthesis.(雷爱文)Abstract: Developing practical strategies to produce high-value chemicals, such as pharmacologically active molecules, from bulk starting materials is an ongoing challenge. One potential route to this goal is the C(sp3)–H fluoroalkylation of natural products, made possible ...
07-12
2023
Single Nanoparticle-Based Nanomachining for Fabrication of Un...
Weiyu Kong, Yang Bao, Liguo Lu, Zhipeng Han, Yifan Zhong, Dr. Ran Zhang, Dr. Yuqiang Li, Prof. Dr. Guoyin Yin.Angewandte Chemie International Edition.(阴国印)Abstract: While chain-walking stimulates wide interest in both polymerization and organic synthesis, site- and stereoselective control of chain-walking on rings is still a challenging task in the realm of organometallic catalysis....
07-04
2023
Electrochemical flow aziridination of unactivated alkenes
Shengchun Wang (王盛淳), Pengjie Wang (王鹏杰), Shu-Jin Li (李树劲), Yi-Hung Chen (陈宜鸿), Zhi-Jun Sun (孙志军), Aiwen Lei (雷爱文).National Science Review.(雷爱文、孙志军、陈宜鸿)Abstract: The Aziridines derived from bioactive molecules may have unique pharmacological activities, making them used in pharmacology (e.g. mitomycin C). Furthermore, the substitution of the epoxide moiety ...
06-27
2023
Recent research progress of all-polymer solar cells based on ...
Tao Wang, Mingxia Chen, Rui Sun, Jie Min.Chem.(闵杰)Abstract: All-polymer solar cells (all-PSCs) have garnered significant interest due to their unique advantages, including significantly improved device stability and mechanical stretchability compared with other types of organic solar cells. Recently, all-PSCs have achieved remarkable improvements in photovoltaic performance. Crucial ...
06-08
2023
Nickel-Catalyzed Regio- and Enantioselective Borylative Coupl...
Zheqi Li, Hongjin Shi, Xueying Chen, Long Peng, Yuqiang. Li* and Guoyin Yin*.J. Am. Chem. Soc.(阴国印、李玉强)Abstract: Chiral boronic esters are a class of versatile building blocks. We describe herein an asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl halides. The success of this asymmetric reaction is ascribed to the application of a ...
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